Highly regioselective and chemoselective titanocene mediated Barbier-type allylation reactions

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URI: https://hdl.handle.net/10481/95657
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Author
Morcillo Martínez, Sara Patricia; Martínez-Peragón, Ángela; Jakoby, Verena; Mota Ávila, Antonio José; Kube, Christian; Justicia Ladrón De Guevara, José; Cuerva Carvajal, Juan Manuel; Gansüuer, Andreas
Editorial
Royal Society of Chemistry
Date
2014-01-06
Referencia bibliográfica
Morcillo Martínez, S.P. et. al. Chem. Commun., 2014, 50, 2211. [https://doi.org/10.1039/C3CC49230C]
Sponsorship
Spanish MICINN (Grants CTQ-2011.22455 and PRI-AIBDE-2011-1122); SFB 813 ‘Chemistry at Spin Centers’
Abstract
Titanocene carboxylate 1 is an excellent chemoselective reagent for unprecedented a-regioselective Barbier-type reactions. It constitutes the first titanocene(III) able to tolerate epoxides and readily reduced carbonyl compounds, such as aromatic and a,b-unsaturated aldehydes.
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Atribución 4.0 Internacional
Except where otherwise noted, this item's license is described as Atribución 4.0 Internacional