Highly regioselective and chemoselective titanocene mediated Barbier-type allylation reactions Morcillo Martínez, Sara Patricia Martínez-Peragón, Ángela Jakoby, Verena Mota Ávila, Antonio José Kube, Christian Justicia Ladrón De Guevara, José Cuerva Carvajal, Juan Manuel Gansüuer, Andreas Titanocene carboxylate 1 is an excellent chemoselective reagent for unprecedented a-regioselective Barbier-type reactions. It constitutes the first titanocene(III) able to tolerate epoxides and readily reduced carbonyl compounds, such as aromatic and a,b-unsaturated aldehydes. 2024-10-08T07:14:05Z 2024-10-08T07:14:05Z 2014-01-06 journal article Morcillo Martínez, S.P. et. al. Chem. Commun., 2014, 50, 2211. [https://doi.org/10.1039/C3CC49230C] https://hdl.handle.net/10481/95657 10.1039/C3CC49230C eng http://creativecommons.org/licenses/by/4.0/ open access Atribución 4.0 Internacional Royal Society of Chemistry