Highly regioselective and chemoselective titanocene mediated Barbier-type allylation reactions

Morcillo Martínez, Sara Patricia; Martínez-Peragón, Ángela; Jakoby, Verena; Mota Ávila, Antonio José; Kube, Christian; Justicia Ladrón De Guevara, José; Cuerva Carvajal, Juan Manuel; Gansüuer, Andreas

doi:10.1039/C3CC49230C

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Identificadores

URI: https://hdl.handle.net/10481/95657

DOI: 10.1039/C3CC49230C

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Editorial

Royal Society of Chemistry

Fecha

2014-01-06

Referencia bibliográfica

Morcillo Martínez, S.P. et. al. Chem. Commun., 2014, 50, 2211. [https://doi.org/10.1039/C3CC49230C]

Patrocinador

Spanish MICINN (Grants CTQ-2011.22455 and PRI-AIBDE-2011-1122); SFB 813 ‘Chemistry at Spin Centers’

Resumen

Titanocene carboxylate 1 is an excellent chemoselective reagent for unprecedented a-regioselective Barbier-type reactions. It constitutes the first titanocene(III) able to tolerate epoxides and readily reduced carbonyl compounds, such as aromatic and a,b-unsaturated aldehydes.

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