Recent progress in the quantitative assessment and interpretation of photoactivity
Metadatos
Mostrar el registro completo del ítemEditorial
Taylor & Francis
Materia
Energy Rate and turnover Photonic yield Quantum and global efficiency Intrinsic kinetics
Fecha
2022-06-20Referencia bibliográfica
Uriel Caudillo-Flores... [et al.] (2022): Recent progress in the quantitative assessment and interpretation of photoactivity, Catalysis Reviews, DOI: [10.1080/01614940.2022.2075535]
Patrocinador
MCIN/AEI PID2019-105490RB-C31; ERDF A way of making Europe; European Commission; Consejo Nacional de Ciencia y Tecnologia (CONACyT) SENER-CONACyT 117373; UGR PPJIA2019-09Resumen
The development of the photo-catalysis field is limited by a
deficient quantitative assessment of photo-activity. The interplay
between mass and momentum transport together with radiative
transfer phenomena taking place at any photo-catalytic reaction
or process makes complex such quantitative assessment. To
reach this goal, the review studies the measurement, meaning,
and analysis of three types of observables. The first family of
observables has the reaction rate and closely connected
observables as the turnover frequency as central pieces.
The second family owns the so-called efficiency observables,
starting from the photonic yield and quantum efficiency of the
reaction and ending in the global efficiency of the process. Finally,
the review studies kinetic constant observables. The contribution
focusses on most rencet contribution analyzing these
observables in terms of their (adequate) measurement conditions
and physico-chemical interpretation, in order to unveil their full
potential in the context of the photo-catalysis field.