Catalytically Active Imine-based Covalent Organic Frameworks for Detoxification of Nerve Agent Simulants in Aqueous Media
Metadatos
Mostrar el registro completo del ítemAutor
Royuela, Sergio; Gil-San Millán, Rodrigo; Mancheño, María J.; Ramos, M. Mar; Segura, Jose L.; Rodríguez Navarro, Jorge Andrés; Zamora, FélixEditorial
Materials
Materia
covalent organic frameworks Catalysis chemical warfare agents detoxification
Fecha
2019-06-19Referencia bibliográfica
Royuela, S., Millán, G. S., Mancheño, M. J., Ramos, M., Segura, J. L., Navarro, J. A., & Zamora, F. (2019). Catalytically Active Imine-based Covalent Organic Frameworks for Detoxification of Nerve Agent Simulants in Aqueous Media. Materials, 12(12), 1974.
Patrocinador
MINECO (MAT2016-77608-C3-1-P and 2-P, CTQ2017-84692-R) and EU FEDER fundingResumen
A series of imine-based covalent organic frameworks decorated in their cavities with
di erent alkynyl, pyrrolidine, and N-methylpyrrolidine functional groups have been synthetized.
These materials exhibit catalytic activity in aqueous media for the hydrolytic detoxification of nerve
agents, as exemplified with nerve gas simulant diisopropylfluorophosphate (DIFP). These preliminary
results suggest imine-based covalent organic frameworks (COFs) as promising materials for
detoxification of highly toxic molecules.