@misc{10481/57357, year = {2019}, month = {6}, url = {http://hdl.handle.net/10481/57357}, abstract = {A series of imine-based covalent organic frameworks decorated in their cavities with di erent alkynyl, pyrrolidine, and N-methylpyrrolidine functional groups have been synthetized. These materials exhibit catalytic activity in aqueous media for the hydrolytic detoxification of nerve agents, as exemplified with nerve gas simulant diisopropylfluorophosphate (DIFP). These preliminary results suggest imine-based covalent organic frameworks (COFs) as promising materials for detoxification of highly toxic molecules.}, organization = {MINECO (MAT2016-77608-C3-1-P and 2-P, CTQ2017-84692-R) and EU FEDER funding}, publisher = {Materials}, keywords = {covalent organic frameworks}, keywords = {Catalysis}, keywords = {chemical warfare agents}, keywords = {detoxification}, title = {Catalytically Active Imine-based Covalent Organic Frameworks for Detoxification of Nerve Agent Simulants in Aqueous Media}, doi = {10.3390/ma12121974}, author = {Royuela, Sergio and Gil-San Millán, Rodrigo and Mancheño, María J. and Ramos, M. Mar and Segura, Jose L. and Rodríguez Navarro, Jorge Andrés and Zamora, Félix}, }