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Discontinuity-enhanced icephobic surfaces for low ice adhesion

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Identificadores
URI: https://hdl.handle.net/10481/95576
DOI: 10.1016/j.jcis.2024.09.205
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Autor
Ibáñez Ibáñez, Pablo Francisco; Stendardo, Luca; Ospina, Catalina; Chaudhary, Rajat; Tagliaro, Irene; Antonini, Carlo
Editorial
Elsevier
Materia
Icephobic
 
Interfacial fracture
 
Durable surfaces
 
Low ice adhesion
 
Fecha
2024-09-26
Referencia bibliográfica
Journal of Colloid and Interface Science 679 (2025) 403–410
Resumen
Hypothesis: Passive low ice-adhesion surfaces are frequently composed of soft materials; however, soft materials potentially present durability issues, which could be overcome by fabricating composite surfaces with patterned rigid and soft areas. Here we propose the innovative concept of discontinuity-enhanced icephobic surfaces, where the stress concentration at the edge between rigid and soft areas, i.e. where discontinuities in elasticity are located, facilitates ice detachment. Experiments: Composite model surfaces were fabricated with controlled rigid-soft ratios and discontinuity line lengths. The ice adhesion values were measured while recording the ice/substrate interface, to unravel the underpinning ice detachment mechanism. The experiments were complemented by numerical simulations that provided a better understanding of the ice detachment mechanism. Findings: It was found that when a surface contains rigid and soft areas, stress is concentrated at the edge between soft and hard areas, i.e. at the discontinuity line, rather than all over the soft or rigid areas. An unexpected nonunidirectional crack propagation was observed for the first time and elucidated. When rigid and deformable materials are present, the crack occurs on the discontinuity line and propagates first on rigid and then on soft areas. Moreover, it was demonstrated that an increase in discontinuities promotes crack initiation and leads to a reduction of ice adhesion.
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