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catena-Poly[oxidanium [tris{μ-[amino(iminio)methyl]phosphonato}zincate(II)]]
dc.contributor.author | Chachlaki, Elpiniki | |
dc.contributor.author | Choquesillo Lazarte, Duane | |
dc.contributor.author | Demadis, Konstantinos D. | |
dc.date.accessioned | 2022-07-20T10:04:55Z | |
dc.date.available | 2022-07-20T10:04:55Z | |
dc.date.issued | 2022 | |
dc.identifier.citation | Chachlaki et al. catena-Poly[oxidanium [tris{l-[amino(iminio)- methyl]phosphonato}zincate(II)]]. IUCrData (2022). 7, x220247 [https://doi.org/10.1107/S2414314622002474] | es_ES |
dc.identifier.uri | http://hdl.handle.net/10481/76203 | |
dc.description | Structural data: full structural data are available from iucrdata.iucr.org | es_ES |
dc.description | Crystallographic Information File (CIF) https://doi.org/10.1107/S2414314622002474/tk4074sup1.cif Contains datablock I | es_ES |
dc.description | Structure factor file (CIF format) https://doi.org/10.1107/S2414314622002474/tk4074Isup2.hkl Contains datablock I | es_ES |
dc.description | MDL mol file https://doi.org/10.1107/S2414314622002474/tk4074Isup3.mol Supplementary material | es_ES |
dc.description | Chemdraw file https://doi.org/10.1107/S2414314622002474/tk4074Isup4.cdx Supplementary material | es_ES |
dc.description.abstract | The crystal structure of the anionic zinc–[amino(iminio)methyl]phosphonate one-dimensional coordination polymer, Zn-AIMP, is reported; the negative charge is balanced by an oxidanium cation (H3O+) to give the composition {(H3O)[Zn(CH4N2PO3)3]}n. The building unit of the coordination polymer comprises a divalent Zn2+ cation (site symmetry \overline3..) and three [amino(iminio)methyl]phosphonate mono-anionic ligands (point group symmetry m). The AIMP ligand exists in a zwitterionic form with a total charge −1 as the phosphonate is fully deprotonated (–PO32−), while the amino(iminio)methyl moiety is protonated (H2N—C—NH2+). | es_ES |
dc.description.sponsorship | Research project ‘Innovative Materials and Applications’ (INNOVAMAT, KA 10694) by the Special Account for Research Grants | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | International Union of Crystallography | es_ES |
dc.rights | Atribución 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | * |
dc.subject | Phosphonate | es_ES |
dc.subject | Coordination polymers | es_ES |
dc.subject | Zinc | es_ES |
dc.subject | One-dimensional network | es_ES |
dc.subject | Crystal structure | es_ES |
dc.title | catena-Poly[oxidanium [tris{μ-[amino(iminio)methyl]phosphonato}zincate(II)]] | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es_ES |
dc.identifier.doi | 10.1107/S2414314622002474 | |
dc.type.hasVersion | info:eu-repo/semantics/publishedVersion | es_ES |