catena-Poly[oxidanium [tris{μ-[amino(iminio)methyl]phosphonato}zincate(II)]]

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URI: http://hdl.handle.net/10481/76203
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Author
Chachlaki, Elpiniki; Choquesillo Lazarte, Duane; Demadis, Konstantinos D.
Editorial
International Union of Crystallography
Materia
Phosphonate
 
Coordination polymers
 
Zinc
 
One-dimensional network
 
Crystal structure
 
Date
2022
Referencia bibliográfica
Chachlaki et al. catena-Poly[oxidanium [tris{l-[amino(iminio)- methyl]phosphonato}zincate(II)]]. IUCrData (2022). 7, x220247 [https://doi.org/10.1107/S2414314622002474]
Sponsorship
Research project ‘Innovative Materials and Applications’ (INNOVAMAT, KA 10694) by the Special Account for Research Grants
Abstract
The crystal structure of the anionic zinc–[amino­(iminio)meth­yl]phospho­nate one-dimensional coordination polymer, Zn-AIMP, is reported; the negative charge is balanced by an oxidanium cation (H3O+) to give the composition {(H3O)[Zn(CH4N2PO3)3]}n. The building unit of the coordination polymer comprises a divalent Zn2+ cation (site symmetry \overline3..) and three [amino(iminio)meth­yl]phospho­nate mono-anionic ligands (point group symmetry m). The AIMP ligand exists in a zwitterionic form with a total charge −1 as the phospho­nate is fully deprotonated (–PO32−), while the amino­(iminio)methyl moiety is protonated (H2N—C—NH2+).
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Atribución 4.0 Internacional
Except where otherwise noted, this item's license is described as Atribución 4.0 Internacional