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dc.contributor.authorMorales Torres, Sergio 
dc.contributor.authorJirglová, Haana
dc.contributor.authorPastrana Martínez, Luisa María 
dc.contributor.authorMaldonado Hodar, Francisco José 
dc.date.accessioned2020-09-10T08:55:36Z
dc.date.available2020-09-10T08:55:36Z
dc.date.issued2020-06-26
dc.identifier.citationMorales-Torres, S., Jirglová, H., Pastrana-Martínez, L. M., & Maldonado-Hódar, F. J. (2020). Influence of Electrostatic Interactions During the Resorcinol-Formaldehyde Polymerization on the Characteristics of Mo-Doped Carbon Gels. Processes, 8(6), 746. [doi: 10.3390/pr8060746]es_ES
dc.identifier.urihttp://hdl.handle.net/10481/63368
dc.description.abstractThe resorcinol (R)-formaldehyde (F) polymerization was carried out in different experimental conditions to obtain RF/Mo doped carbon xerogels with different morphology, porosity and nature and dispersion of metal. Attractive or repulsive electrostatic interactions were forced in the starting aqueous solution of RF-monomers using different synthesis conditions, namely, combinations of cationic or anionic surfactants, Mo-precursors and pH values. The results showed that when both cationic surfactant and Mo-precursor were used at neutral pH, attractive interactions with the anionic RF-macromolecules are favored during polymerization and the final carbon xerogel exhibited the most developed porosity and the strongest Mo-organic phase interaction, leading to deeper Mo-phase reduction during carbonization and the formation of highly-dispersed crystalline nanoparticles of Mo2C. On the contrary, the use of both anionic surfactant and Mo-precursor leads to repulsive interactions, which generates less porous carbon gels with a Mo-phase formed by large MoO3 platelet structures and low Mo-surface contents. RF/Mo-doped gels with intermediate properties were obtained by combining cationic and anionic surfactants, metal precursors or both. After carbonization, the obtained materials would be suitable to be used directly as catalysts with different physicochemical properties and active phases.es_ES
dc.description.sponsorshipSpanish Project from ERDF/Ministry of Science, Innovation and Universities-State Research Agency RTI2018-099224-B-I00es_ES
dc.language.isoenges_ES
dc.publisherMDPIes_ES
dc.rightsAtribución 3.0 España*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.subjectResorcinol-formaldehyde polymerizationes_ES
dc.subjectSurfactants es_ES
dc.subjectMo-dopinges_ES
dc.subjectChemical interactionses_ES
dc.subjectCarbon xerogelses_ES
dc.subjectPhysicochemical propertieses_ES
dc.subjectMetal nanoparticleses_ES
dc.titleInfluence of Electrostatic Interactions During the Resorcinol-Formaldehyde Polymerization on the Characteristics of Mo-Doped Carbon Gelses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.identifier.doi10.3390/pr8060746


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Atribución 3.0 España
Except where otherwise noted, this item's license is described as Atribución 3.0 España