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Slow Magnetic Relaxation in a Co (II)–Y (III) Single‐Ion Magnet with Positive Axial Zero‐Field Splitting

dc.contributor.authorColacio Rodríguez, Enrique 
dc.date.accessioned2020-07-03T07:33:26Z
dc.date.available2020-07-03T07:33:26Z
dc.date.issued2013-08-26
dc.identifier.citationPublished version: Colacio, E, Ruiz, J, Ruiz, E, Cremades, E, Krzystek, J, Carretta, S, Cano, J, Guidi, T, Wernsdorfer, W & Brechin, EK 2013, 'Slow Magnetic Relaxation in a Co(II) -Y(III) Single-Ion Magnet with Positive Axial ZeroField Splitting', Angewandte Chemie International Edition, vol. 52, no. 35, pp. 9130-9134. [https://doi.org/10.1002/anie.201304386]es_ES
dc.identifier.urihttp://hdl.handle.net/10481/62844
dc.descriptionThis work was supported by the MINECO (Spain) (Project CTQ2011-24478), the Junta de Andalucía (FQM-195 and Project of excellence P08-FQM-03705), and the University of Granada. E.R. and E.Cr. thank MINECO grant No. CTQ2011-23862-C02-01 and Generalitat de Catalunya grant No. 2009SGR-1459, for financial support. We would like to thank Prof. Liviu Chibotaru for providing us the SINGLE_ANISO program and Dr. Andrew Ozarowski for the EPR simulation software. E.K.B. thanks the EPSRC and Leverhulme Trust for financial support. The NHMFL is funded by the NSF, DoE, and the state of Florida. J.C. acknowledges financial support by the Spanish Ministerio de Ciencia e Innovación through projects CTQ2010-15364, Molecular Nanoscience (Consolider Ingenio CSD2007-00010), and Generalitat Valenciana (PROMETEO/2009/108). W.W. acknowledges the ARN-PNANO project MolNanoSpin No. ANR-08-NANO- 002 and the ERC Advanced Grant MolNanoSpin No. 226558. J.K. acknowledges NSF grant DMR 1157490.es_ES
dc.description.abstractThe complex [Co(µ-L)(µ-OAc)Y(NO3)2], in which the Co(II) ion exhibits a D value of ~+45 cm-1 as determined by magnetic and inelastic neutron scattering experiments, exhibits slow magnetic relaxation and Single-Ion Magnet behaviour.es_ES
dc.description.sponsorshipMINECO (Spain) CTQ2011-24478es_ES
dc.description.sponsorshipJunta de Andalucía FQM-195 P08-FQM-03705es_ES
dc.description.sponsorshipUniversity of Granadaes_ES
dc.description.sponsorshipMINECO CTQ2011-23862-C02-01es_ES
dc.description.sponsorshipGeneralitat de Catalunya 2009SGR-1459es_ES
dc.description.sponsorshipEngineering & Physical Sciences Research Council (EPSRC)es_ES
dc.description.sponsorshipLeverhulme Trustes_ES
dc.description.sponsorshipNational Science Foundation (NSF) DMR 1157490es_ES
dc.description.sponsorshipUnited States Department of Energy (DOE)es_ES
dc.description.sponsorshipState of Floridaes_ES
dc.description.sponsorshipInstituto de Salud Carlos III Spanish Government CTQ2010-15364 CSD2007-00010es_ES
dc.description.sponsorshipGeneralitat Valenciana PROMETEO/2009/108es_ES
dc.description.sponsorshipARN-PNANO project MolNanoSpin ANR-08-NANO-002es_ES
dc.description.sponsorshipEuropean Research Council (ERC) 226558es_ES
dc.description.sponsorshipEngineering & Physical Sciences Research Council (EPSRC) EP/L010615/1es_ES
dc.language.isoenges_ES
dc.publisherWileyes_ES
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subjectCo(II)es_ES
dc.subjectSingle ion magnetes_ES
dc.subjectCompartmental ligandes_ES
dc.subjectINSes_ES
dc.subjectPositive axial ZFSes_ES
dc.titleSlow Magnetic Relaxation in a Co (II)–Y (III) Single‐Ion Magnet with Positive Axial Zero‐Field Splittinges_ES
dc.typejournal articlees_ES
dc.rights.accessRightsopen accesses_ES
dc.identifier.doi10.1002/anie.201304386
dc.type.hasVersionAMes_ES


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