Slow Magnetic Relaxation in a Co (II)–Y (III) Single‐Ion Magnet with Positive Axial Zero‐Field Splitting

Colacio Rodríguez, Enrique

doi:10.1002/anie.201304386

Slow_Magnetic_Relaxation_in_a_CoII.pdf (687.9Kb)

Identificadores

URI: http://hdl.handle.net/10481/62844

DOI: 10.1002/anie.201304386

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Editorial

Wiley

Materia

Co(II)

Single ion magnet

Compartmental ligand

INS

Positive axial ZFS

Date

2013-08-26

Referencia bibliográfica

Published version: Colacio, E, Ruiz, J, Ruiz, E, Cremades, E, Krzystek, J, Carretta, S, Cano, J, Guidi, T, Wernsdorfer, W & Brechin, EK 2013, 'Slow Magnetic Relaxation in a Co(II) -Y(III) Single-Ion Magnet with Positive Axial ZeroField Splitting', Angewandte Chemie International Edition, vol. 52, no. 35, pp. 9130-9134. [https://doi.org/10.1002/anie.201304386]

Sponsorship

MINECO (Spain) CTQ2011-24478; Junta de Andalucía FQM-195 P08-FQM-03705; University of Granada; MINECO CTQ2011-23862-C02-01; Generalitat de Catalunya 2009SGR-1459; Engineering & Physical Sciences Research Council (EPSRC); Leverhulme Trust; National Science Foundation (NSF) DMR 1157490; United States Department of Energy (DOE); State of Florida; Instituto de Salud Carlos III Spanish Government CTQ2010-15364 CSD2007-00010; Generalitat Valenciana PROMETEO/2009/108; ARN-PNANO project MolNanoSpin ANR-08-NANO-002; European Research Council (ERC) 226558; Engineering & Physical Sciences Research Council (EPSRC) EP/L010615/1

Abstract

The complex [Co(µ-L)(µ-OAc)Y(NO3)2], in which the Co(II) ion exhibits a D value of ~+45 cm-1 as determined by magnetic and inelastic neutron scattering experiments, exhibits slow magnetic relaxation and Single-Ion Magnet behaviour.

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Except where otherwise noted, this item's license is described as Atribución-NoComercial-SinDerivadas 3.0 España