Sensitive spectrofluorometric determination of vanadium with sodium 1,2-dihydroxyanthraquinone-3-sulfonate in cationic micellar medium

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URI: http://hdl.handle.net/10481/32425
ISSN: 0910-6340
ISSN: 1348-2246
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Author
García Campaña, Ana María; Alés Barrero, Fermín; Román Ceba, Manuel
Editorial
Japan Society for Analytical Chemistry (JSAC)
Materia
Spectrofluorometry
 
Sodium 1,2-dihydroxyanthraquinone-3-sulfonate
 
Vanadium determination
 
Micellar medium
 
Date
1996
Referencia bibliográfica
García Campaña, A.M.; Alés Barrero, F.; Román Ceba, M. Sensitive spectrofluorometric determination of vanadium with sodium 1,2-dihydroxyanthraquinone-3-sulfonate in cationic micellar medium. Analytical Sciences, 12(4): 647-651 (1996). [http://hdl.handle.net/10481/32425]
Abstract
A spectrofluorometric method is described for the determination of vanadium(V) based on its complexation reaction with sodium 1, 2-dihydroxyanthraquinone-3-sulfonate in presence of hexadecyltrimethylammonium bromide. The fluorescence is monitored at 607nm with excitation at 505nm. The experimental variables and interferences in this determination have been studied. The detection limit is 3.0ng ml-1 and the linear range is between 10 and 1000ng ml-1. The method has been applied to the determination of vanadium in clams and seawater with satisfactory precision.
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