| dc.contributor.author | Cirujano, Francisco G. | |
| dc.contributor.author | López-Maya, Elena | |
| dc.contributor.author | Rodríguez-Albelo, Luisa Marleny | |
| dc.contributor.author | Barea Martínez, Elisa María | |
| dc.contributor.author | Rodríguez Navarro, Jorge Andrés | |
| dc.contributor.author | De Vos, Dirk E | |
| dc.date.accessioned | 2026-02-16T08:41:10Z | |
| dc.date.available | 2026-02-16T08:41:10Z | |
| dc.date.issued | 2017-06-19 | |
| dc.identifier.citation | Cirujano, F. G.; López-Maya, E.; Rodríguez-Albelo, L. M. [et al]. (2017). Selective One-Pot Two-Step C–C Bond Formation using Metal–Organic Frameworks with Mild Basicity as Heterogeneous Catalysts. ChemCatChem, Volume 9, issue 21, pp. 4019 – 4023. https://doi.org/10.1002/cctc.201700784 | es_ES |
| dc.identifier.issn | 1867-3899 | |
| dc.identifier.issn | 1867-3880 | |
| dc.identifier.uri | https://hdl.handle.net/10481/111009 | |
| dc.description | Spanish Ministry of Economy and Competitiveness (MINECO)
under the grant number CTQ2014-53486-R, Fonds Wetenschappelijk Onderzoek (F.W.O). for project funding under the grant
number G.0256.14N and the European Commission-Horizon 2020
under the Marie Sklodowska–Curie Individual Fellowship grant
agreement number750391(Project acronym SINMOF) are
acknowledged for financial support. | es_ES |
| dc.description.abstract | Copper-ion-exchanged nickel pyrazolate frameworks behave as selective heterogeneous catalysts for the one-pot, two-step (Henry reaction/Michael type addition) synthesis of neuroactive pharmaceutical intermediates starting from nitromethane and
benzaldehyde. Tuning the basicity of multifunctional metal–organic framework catalysts through ion exchange with copper(-
II) cations allows the tandem C@C bond-forming process to be selectively directed towards the desired pharmaceutical intermediate. | es_ES |
| dc.description.sponsorship | Universidad de Granada (Dpto de Química Inorgánica) | es_ES |
| dc.description.sponsorship | Spanish Ministry of Economy and Competitiveness (CTQ2014-53486-R) | es_ES |
| dc.description.sponsorship | Fonds Wetenschappelijk Onderzoek (G.0256.14N) | es_ES |
| dc.description.sponsorship | Horizon 2020, Marie Sklodowska–Curie (750391, project acronym SINMOF) | es_ES |
| dc.language.iso | eng | es_ES |
| dc.publisher | Wiley | es_ES |
| dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
| dc.subject | Tunable basicity | es_ES |
| dc.subject | C-C bond formation | es_ES |
| dc.subject | Heterogeneous catalysis | es_ES |
| dc.title | Selective One-Pot Two-Step C-C Bond Formation using Metal–Organic Frameworks with Mild Basicity as Heterogeneous Catalysts | es_ES |
| dc.type | journal article | es_ES |
| dc.rights.accessRights | open access | es_ES |
| dc.identifier.doi | 10.1002/cctc.201700784 | |
| dc.type.hasVersion | VoR | es_ES |