Show simple item record

dc.contributor.authorKowalski, Andrew S.es_ES
dc.date.accessioned2017-12-04T08:04:13Z
dc.date.available2017-12-04T08:04:13Z
dc.date.issued2017-07-05
dc.identifier.citationKowalski, A.S. The boundary condition for vertical velocity and its interdependence with surface gas exchange. Atmospheric Chemistry and Physics, 17: 8177-8187 (2017). [http://hdl.handle.net/10481/48369]es_ES
dc.identifier.issn1680-7316
dc.identifier.issn1680-7324
dc.identifier.urihttp://hdl.handle.net/10481/48369
dc.description.abstractThe law of conservation of linear momentum is applied to surface gas exchanges, employing scale analysis to diagnose the vertical velocity (w) in the boundary layer. Net upward momentum in the surface layer is forced by evaporation (E) and defines non-zero vertical motion, with a magnitude defined by the ratio of E to the air density, as w = E/ρ. This is true even right down at the surface where the boundary condition is w|0 = E/ρ|0 (where w|0 and ρ|0 represent the vertical velocity and density of air at the surface). This Stefan flow velocity implies upward transport of a non-diffusive nature that is a general feature of the troposphere but is of particular importance at the surface, where it assists molecular diffusion with upward gas migration (of H2O, for example) but opposes that of downward-diffusing species like CO2 during daytime. The definition of flux–gradient relationships (eddy diffusivities) requires rectification to exclude non-diffusive transport, which does not depend on scalar gradients. At the microscopic scale, the role of non-diffusive transport in the process of evaporation from inside a narrow tube – with vapour transport into an overlying, horizontal airstream – was described long ago in classical mechanics and is routinely accounted for by chemical engineers, but has been neglected by scientists studying stomatal conductance. Correctly accounting for non-diffusive transport through stomata, which can appreciably reduce net CO2 transport and marginally boost that of water vapour, should improve characterisations of ecosystem and plant functioning.en_EN
dc.description.sponsorshipInvestigation into this matter was funded by Spanish national project GEISpain (CGL2014-52838-C2-1-R).en_EN
dc.language.isoenges_ES
dc.publisherEuropean Geosciences Uniones_ES
dc.rightsCreative Commons Attribution-NonCommercial-NoDerivs 3.0 Licensees_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es_ES
dc.subjectTransporten_EN
dc.subjectStomataen_EN
dc.subjectSurface gas exchangesen_EN
dc.subjectVertical velocityen_EN
dc.subjectEcosystemsen_EN
dc.titleThe boundary condition for vertical velocity and its interdependence with surface gas exchangeen_EN
dc.typeinfo:eu-repo/semantics/articleen_EN
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen_EN
dc.identifier.doi10.5194/acp-17-8177-2017


Files in this item

[PDF]

This item appears in the following Collection(s)

Show simple item record

Creative Commons Attribution-NonCommercial-NoDerivs 3.0 License
Except where otherwise noted, this item's license is described as Creative Commons Attribution-NonCommercial-NoDerivs 3.0 License