Compuestos de fosfito de trialilo con iones metálicos de configuración d8 Suárez Cardeso, J. M. Nyholm, Ronald S. All the attempts to prepare complexes of triallyI phosphite with Pt (II) were unsuccessful. However, the reactions of this ligand with Rh (1) and Pd (II) ,take place and synthesis condi.tions are described. The composition and nature of the insulated complexes was elucid·ated by elemental analysis, molecular weight measurements and infrared and nuclear magnetic resonanse data. The triallylphosphite reaction with RhCI goes to the synthesis of chloro (triallylphosphite) rhodium (1), with all the olefin groups coordinated to the rhodium, but with Rh el (PPh3) the trans-chlorocarbonYI bis (Triphenylphosphine) rhodium (1) is insulated. On the other hand, equivalen,t amounts of (CfiH5CN)2PdCI and ligand react ,to g:ve bisallyldi-f L--chloropalladium (Il). 2023-05-26T08:19:24Z 2023-05-26T08:19:24Z 1973-12-20 info:eu-repo/semantics/article Suárez Cardeso, J. M.; Nyholm, Ronald S. Compuestos de fosfito de trialilo con iones metálicos de configuración d8. Ars Pharm, 15(Único): 111-23 (1974). [https://revistaseug.ugr.es/index.php/ars/article/view/24816] 2340-9894 https://hdl.handle.net/10481/81849 spa http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess Attribution-NonCommercial-NoDerivatives 4.0 Internacional Universidad de Granada, Facultad de Farmacia.