Rational design of carborane-based Cu2-paddle wheel coordination polymers for increased hydrolytic stability

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URI: http://hdl.handle.net/10481/72493
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Auteur
Li, Zhen; Choquesillo Lazarte, Duane
Editorial
Royal Society of Chemistry
Date
2021-12-09
Referencia bibliográfica
Dalton Trans., 2022,51, 1137-1143. DOI: [10.1039/d1dt04065k]
Patrocinador
Spanish Government; European Commission PID2019-106832RB-I00; MICINN through the Severo Ochoa Program for Centers of Excellence for the FUNFUTURE CEX2019-000917-S; Generalitat de Catalunya; General Electric 2017/SGR/1720; MCIU/AEI/FEDER, UE PGC2018-102047-B-I00; China Scholarship Council 201808310071
Résumé
A new unsymmetric carborane-based dicarboxylic linker provided a 1D Cu2-paddle wheel coordination polymer (2) with much higher hydrolytic stability than the corresponding 2D Cu2-paddle wheel polymer (1), obtained from a related more symmetrical carborane-based linker. Both 1 and 2 were used as efficient heterogeneous catalysts for a model aza-Michael reaction but only 2 can be reused several times without significant degradation in catalytic activity.
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Atribución-NoComercial 3.0 España
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