Aggregation-induced emission of [3]cumulenes functionalized with heptagon-containing polyphenylenes

Identificadores
URI: http://hdl.handle.net/10481/51955
ISSN: 1359-7345
ISSN: 1364-548X
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Auteur
García Jiménez, Vicente; Tapia Martín, Rubén; Medel Miranda, Miguel Ángel; Mariz, Inês F. A.; Ribeiro, Tânia; Blanco Suárez, Víctor; Cuerva Carvajal, Juan Manuel; Maçôas, Ermelinda; González Campaña, Araceli
Editorial
Royal Society of Chemistry
Materia
Aggregated-induced emission
 
Cumulenes
 
Date
2018-03-06
Referencia bibliográfica
García Jiménez, V.; et al. Aggregation-induced emission of [3]cumulenes functionalized with heptagon-containing polyphenylenes. Chemical Communications, online (2018). [ http://hdl.handle.net/10481/51955]
Patrocinador
European Research Council (ERC) under the European Union's Horizon 2020 research and innovation program (ERC-2015 -677023).; Ministerio de Economía y Competitividad (MINECO, Spain – FEDER) (CTQ2015-70283-P, CTQ2014-53598-R, RyC-2013-12943).; Fundação para a Ciência e a tecnologia (Portugal, IF/00759/2013, SFRH/BPD/75782/2011,SFRH/BPD/96707/2013,UID/NAN/50024/2013).
Résumé
We report the luminiscence at room temperature by aggregate formation of [3]cumulenes functionalized with propeller-like heptagon-containing polyphenylenes. These endgroups turn on the emission of a [3]cumulene by steric protection and restriction of their intramolecular rotations in the aggregates.
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