@misc{10481/68590, year = {2020}, month = {9}, url = {http://hdl.handle.net/10481/68590}, abstract = {Thiele (Th) and tetrabenzo-Chichibabin (TBC) derivatives with terminal dibenzocycloheptatriene (DBHept) units were prepared. A clear correlation between their electronic and molecular structures was stablished. Insights into their closed- or open-shell ground states were gained, where particular contribution of the heptagonal carbocycles as end-groups was proved. Remarkably, a thermally accessible triplet diradical configuration was confirmed for theDBHept-TBCcompound.}, organization = {MICIU/FEDER/AEI, Spain PG2018-101181-B-I00 PGC2018-095808B-I00 MAT2016-80826-R FIP-2018-HECTIC-PTM Prometeo2019/076}, organization = {MICIU/FEDER/AEI, Spain ("Severo Ochoa" Programme for Centres of Excellence in RD) SEV-2015-0496}, organization = {European Research Council (ERC) 677023}, organization = {DGR (Catalunya) 2017-SGR-918}, organization = {Swiss National Science Foundation (SNSF) PZ00P2_174175}, publisher = {Royal Society of Chemistry}, title = {Dibenzocycloheptatriene as end-group of Thiele and tetrabenzo-Chichibabin hydrocarbons}, doi = {10.1039/d0cc04489j}, author = {García Jiménez, Vicente and Blanco Suárez, Víctor and Cuerva Carvajal, Juan Manuel and González Campaña, Araceli}, }