TY - JOUR AU - Arjona, O. AU - Plumet, J. PY - 1995 SN - 0004-2927 UR - https://hdl.handle.net/10481/83673 AB - The total syntheses of the antibiotic validamine an its three diastereomers have been acomplished and their racemic penta-N-O-acetates via stereocontrolled nucleophilic epoxidation of polihydroxylated cyclohexenyl sulfones, obtained from... AB - La epoxidación nucleofilica estereocontrolada de ciclohexenil sulfonas polidroxiladas, obtenidas a partir de (fenilsulfonil)-7-oxabiciclo[2,2, l ] heptano s conduce a la síntesis total del antibiótico validarnina y sus tres diastereoisómeros. La... LA - eng PB - Universidad de Granada, Facultad de Farmacia. TI - A stereodivergent access to naturally occurring aminocarbasugars from (Phenylsulfonyl)-7 -oxa-bicyclo[2.2.1 ]heptane derivatives. Total synthesis of ( + )-Validamine and its CI and C2 stereoisomers ER -