TY - GEN AU - Díaz Ortega, Ismael Francisco AU - Herrera Martínez, Juan Manuel AU - Dey, Sourav AU - Nojiri, Hiroyuki AU - Rajaraman, Gopalan AU - Colacio Rodríguez, Enrique PY - 2020 UR - https://hdl.handle.net/10481/109795 AB - We report here a new DyIII-SIM [Dy(OPCy3)2(H2O)5](CF3SO3)3·2OPCy3 (OPCy3 = triclohexylphosphine oxide) with pentagonal bipyramidal geometry, which exhibits a blocking temperature TB = 8.5 K and an anisotropy barrier Ueff = 562 K. Ab initio... LA - eng PB - Royal Society of Chemistry, Chinese Chemical Society KW - Single Molecule Magnets KW - Molecular Magnetism KW - Dysprosium KW - Pentagonal bipyramidal geometry TI - The effect of the electronic structure and flexibility of the counterions on magnetization relaxation in [Dy(L)2(H2O)5]3+ (L = phosphine oxide derivative) pentagonal bipyramidal SIMs. DO - 10.1039/c9qi01412h ER -