Improved Performance of a Europium-based Metal-Organic Framework for Cyanosilylation of Demanding Ketones Pérez, Juana M. Echenique Errandonea, Estitxu Rojas Macías, Sara Choquesillo Lazarte, Duane Seco, José M. López-Vargas, Mireya E. Rodríguez Diéguez, Antonio Fernández, Ignacio cyanosilylation europium heterogeneous catalysis Solvothermally promoted assembly of the multifunctional 3-amino-4-hydroxybenzoic acid ligand with the corresponding Eu salt gives rise to the formation of a porous metal-organic framework with the general formula {[Eu5L6(OH)3(H2O)3] ⋅ 5DMF}n (1) that has been tested as heterogeneous catalyst for the cyanosilylation of a broad scope of ketones in solvent-free conditions, using the lowest catalyst loading of 0.5 mol% ever reported, and exhibiting no leak and high recyclability. 2024-12-04T07:55:45Z 2024-12-04T07:55:45Z 2022-10-25 journal article J. M. Pérez, E. Echenique-Errandonea, S. Rojas, D. Choquesillo-Lazarte, J. M. Seco, M. E. López-Vargas, A. Rodríguez-Diéguez, I. Fernández, ChemCatChem 2022, 14, e202200967. https://hdl.handle.net/10481/97676 10.1002/cctc.202200967 eng http://creativecommons.org/licenses/by/4.0/ open access Atribución 4.0 Internacional Wiley