Copper(I) complexes as alternatives to iridium(III) complexes for highly efficient oxygen sensing† Medina Rodríguez, Santiago Orriach Fernández, Francisco José Poole, Christopher Kumar, Prashant Torre Vega, Ángel De La Fernández Sánchez, Jorge Fernando Baranoff, Etienne Fernández Gutiérrez, Alberto The complex [Cu(xantphos)(dmp)][PF6] (dmp = 2,9-dimethyl-1,10-phenanthroline) in a nanostructured metal oxyde matrix shows better sensitivity to oxygen (KSV = 9.74 ± 0.87 kPa−1 between 0 and 1 kPa pO2 and 5.59 ± 0.15 kPa−1 between 0 and 10 kPa pO2) than cyclometallated iridium complexes in the same conditions. 2024-10-08T07:36:51Z 2024-10-08T07:36:51Z 2015-06-10 journal article Medina ROdríguez, S. et. al. Chem. Commun., 2015, 51, 11401. [https://doi.org/10.1039/C5CC04326C] https://hdl.handle.net/10481/95661 10.1039/C5CC04326C eng http://creativecommons.org/licenses/by-nc/4.0/ open access Atribución-NoComercial 4.0 Internacional Royal Society of Chemistry