Curved Nanographenes as Stoppers in a [2]Rotaxane with Two- Photon Excited Emission Domínguez Codesal, Marcos H. G David, Arthur I. M. Santos, Carla Álvaro-Martins, Maria J. Maçôas, Ermelinda G. Campaña, Araceli Blanco Suárez, Víctor Heptagon-containing distorted nanographenes are used as stoppers for the capping of a [2]rotaxane through a Michael-type addition reaction to vinyl sulfone groups. These curved aromatics are bulky enough to prevent the disassembly of the rotaxane but also give emissive and nonlinear (two-photon absorption and emission) optical properties to the structure. 2024-07-29T10:07:14Z 2024-07-29T10:07:14Z 2024-06-22 journal article Domínguez Codesal, M. et. al. J. Org. Chem. 2024, 89, 9344−9351. [https://doi.org/10.1021/acs.joc.4c00486] https://hdl.handle.net/10481/93535 10.1021/acs.joc.4c00486 eng http://creativecommons.org/licenses/by/4.0/ open access Atribución 4.0 Internacional ACS Publications