Ionic Strength Effect in the Equilibrium and Rheological Behavior of an Amphiphilic Triblock Copolymer at the Air/Solution Interface Carbone, Carlo Guzmán, Eduardo Maldonado Valderrama, Julia G. Rubio, Ramón Ortega Gómez, Francisco Dilational rheology Electrocapillary waves Interfacial tension This study investigates the effect of an inert salt (NaCl) on the equilibrium interfacial tension and dilatational modulus of Pluronic F-68 copolymer, a triblock copolymer consisting of two terminal blocks of poly(ethylene oxide) and a less hydrophilic central block of poly(propylene oxide). Interfacial tension measurements were carried out using a surface force balance and a drop shape tensiometer, while rheological measurements were carried out in two different frequency ranges. This involved the use of the oscillatory barrier/droplet method and electrocapillary wave measurements, complemented by an appropriate theoretical framework. This work aimed to elucidate the influence of NaCl on the interfacial behavior of Gibbs monolayers of Pluronic F-68. In addition, this study highlights some of the technical and theoretical limitations associated with obtaining reliable dilatational rheological data at high frequencies (<1 kHz) using electrocapillary wave measurements. The results provide valuable insights into the interplay between salt presence and interfacial properties of Pluronic F-68 and highlight the challenges of obtaining accurate dilatational rheological data under specific measurement conditions. 2024-06-04T10:09:27Z 2024-06-04T10:09:27Z 2024-03-01 journal article Carbone, C.; Guzmán, E.; Maldonado-Valderrama, J.; Rubio, R.G.; Ortega, F. Ionic Strength Effect in the Equilibrium and Rheological Behavior of an Amphiphilic Triblock Copolymer at the Air/Solution Interface. Colloids Interfaces 2024, 8, 16. https://doi.org/10.3390/colloids8020016 https://hdl.handle.net/10481/92312 10.3390/colloids8020016 eng info:eu-repo/grantAgreement/EC/H2020/MSC 955612 http://creativecommons.org/licenses/by/4.0/ open access Atribución 4.0 Internacional MDPI