Metal−Organic Frameworks Based on a Janus-Head Biquinoline Ligand as Catalysts in the Transformation of Carbonyl Compounds into Cyanohydrins and Alcohols Pérez, Juana M. Morales Cámara, Samuel Ruiz Cuevas, Noelia Choquesillo Lazarte, Duane Abdelkader Fernández, Víctor Karim Rodríguez Diéguez, Antonio Rojas Macías, Sara A new family of metal−organic frameworks (MOFs) named GR-MOFs with the chemical formula {[Mx(BCA)y]- (H2O)z(DMF)w} (x,y,z,w: 1,1,2,0; 1,1.5,0,1; 1,2,2,1; and 1,1,0,2 for GR-MOF-11 to 14, respectively) based on s-block [M: Sr (GRMOF- 11), Ba (GR-MOF-14)] and d-block [M: Y (GR-MOF-12) and Cd (GR-MOF-13)] metals together with the biquinoline ligand 2,2′-bicinchoninic acid (H2BCA) has been synthetized by a solvothermal route and fully characterized by elemental and thermogravimetric analysis, Fourier transform infrared spectroscopy, photoluminescence, particle size distribution through optical microscopy, electrophoretic mobility, and finally, X-ray singlecrystal and powder diffraction. The structural characterization reveals that these 2D and 3D MOFs possess a rich variety of coordination modes that maintained the Janus-head topology on the ligand in most of the cases. The new MOFs were studied in the catalyzed cyanosilylation and hydroboration of an extensive group of aldehydes and ketones, wherein the s-block metal-based MOFs GR-MOF-11 and GR-MOF-14 provided the highest efficiency ever reported in the MOF-catalyzed cyanosilylation of carbonyl compounds by using only 0.5 mol % of catalyst loading, room temperature, and solvent-free conditions. Furthermore, the hydroboration of ketones has been reported for the first time with this type of s-block metal catalysts obtaining from moderate to good conversions. 2023-01-13T11:41:58Z 2023-01-13T11:41:58Z 2022-11-08 info:eu-repo/semantics/article Cryst. Growth Des. 2022, 22, 12, 7395–7404. [https://doi.org/10.1021/acs.cgd.2c00985] https://hdl.handle.net/10481/78975 10.1021/acs.cgd.2c00985 eng http://creativecommons.org/licenses/by/4.0/ info:eu-repo/semantics/openAccess Atribución 4.0 Internacional American Chemical Society