Roman brick production technologies in Padua (Northern Italy) along the Late Antiquity and Medieval Times: Durable bricks on high humid environs Pérez Monserrat, Elena Mercedes Cultrone, Giuseppe V. High humid environs High-temperature phases Historic bricks reuses Mg- and Ca-rich clays Secondary calcite Zeolite hydration products Production technologies of Roman to Medieval times bricks on the city of Padua were addressed by means of a multi-analytical approach, consisting in Spectrophotometry, X-Ray Fluorescence (XRF), Powder X-Ray Diffraction (PXRD), Polarized Optical Microscopy (POM) and Scanning Electron Microscopy (SEM- EDS). The Early-Christian (5-6 th centuries) and Romanesque (12-13 th centuries) areas of the Basilica of Saint Justine of Padua (5/6-16 th centuries), and the remains of the Roman necropolis (1-3/4 th centuries) still preserved under the basilica, were selected to collect the bricks in order to define possible differences between the materials used for the various building phases. The walls are mainly shaped by yellow (with pale and dark hue) and beige colored bricks with an overall good conservation state. The ceramic bodies of this type of bricks showed the development of high-temperature phases but a low sintering degree was achieved. Moreover, secondary phases such as zeolites and calcite were formed, within almost the pale-yellow bodies and intensively precipitated through the groundmass of the beige bricks, respectively. Mg-rich calcareous clays and chloritic-illitic clays were used, firing temperatures of or over 900 °C were reached and more porous ceramic bodies were produced when higher was the carbonate content on the raw clays. A lesser carbonate content of the base clays and/or the decrease in the firing temperatures were the main technological modifications progressively accomplished, leading to color changes on the ceramic bodies from yellow to beige hue. The Roman production technologies might be largely inherited by the brick makers during the Late Antiquity and Medieval times in the city and the reuse of more an- cient bricks during the Medieval Times was confirmed. Such reuse operations have allowed to observe that under high humid conditions the yellow hue bricks have been rather good preserved, while when exposed to insolation and fluctuations of the environmental conditions a significant granular disaggrega- tion -with the concomitance darkening of the color pastes- is developed. The color of bricks may entail an identifier of a specific construction period of the city and durable bricks from local clays, especially suitable for high humidity areas and that may preserve the aesthetical values of the city of Padua, may be currently produced. 2022-07-28T07:53:05Z 2022-07-28T07:53:05Z 2022-01-21 journal article Elena Mercedes Pérez-Monserrat... [et al.]. Roman brick production technologies in Padua (Northern Italy) along the Late Antiquity and Medieval Times: Durable bricks on high humid environs, Journal of Cultural Heritage, Volume 54, 2022, Pages 12-20, ISSN 1296-2074, [https://doi.org/10.1016/j.culher.2022.01.007] http://hdl.handle.net/10481/76401 10.1016/j.culher.2022.01.007 eng info:eu-repo/grantAgreement/EC/H2020/836122 http://creativecommons.org/licenses/by-nc-nd/4.0/ open access Attribution-NonCommercial-NoDerivatives 4.0 Internacional Elsevier