Textile/Metal–Organic-Framework Composites as Self-Detoxifying Filters for Chemical-Warfare Agents López Maya, Elena Montoro, Carmen Rodríguez-Albelo, Luisa Marleny Aznar Cervantes, Salvador D. Lozano-Pérez, Antonio Abel Cenis, Jose Luis Barea Martínez, Elisa María Rodríguez Navarro, Jorge Andrés Heterogeneous catalysis Nerve agents Hydrolysis Inside Cover: Textile/Metal–Organic-Framework Composites as Self-Detoxifying Filters for Chemical-Warfare Agents (Angew. Chem. Int. Ed. 23/2015) Elena López-Maya, Dr. Carmen Montoro, Dr. L. Marleny Rodríguez-Albelo, Dr. Salvador D. Aznar Cervantes, Dr. A. Abel Lozano-Pérez, Prof. José Luis Cenís, Dr. Elisa Barea, Prof. Jorge A. R. Navarro Page: 6654 First Published: 04 May 2015 We thank the Spanish Ministries of Economy (CTQ2011-22787/ PPQ, CTQ2014-53486-R) and Defense (COINCIDENTE), MC-IIF (LMRA), Junta de Andalucia (P09-FQM-4981) and ERDF Operative Program of the Region of Murcia 2007–2013 (AALP) for funding. The current technology of air-filtration materials for protection against highly toxic chemicals, that is, chemical-warfare agents, is mainly based on the broad and effective adsorptive properties of hydrophobic activated carbons. However, adsorption does not prevent these materials from behaving as secondary emitters once they are contaminated. Thus, the development of efficient self-cleaning filters is of high interest. Herein, we report how we can take advantage of the improved phosphotriesterase catalytic activity of lithium alkoxide doped zirconium(IV) metal–organic framework (MOF) materials to develop advanced self-detoxifying adsorbents of chemicalwarfare agents containing hydrolysable P-F, P-O, and C-Cl bonds. Moreover, we also show that it is possible to integrate these materials onto textiles, thereby combining air-permeation properties of the textiles with the self-detoxifying properties of the MOF material. 2026-02-16T07:31:11Z 2026-02-16T07:31:11Z 2015-05-07 journal article López Maya, E.; Montoro, C.; Rodríguez-Albelo, L. M. [et al.] (2015). Angewandte Chemie International Edition, Volume 54, Issue 23 pp. 6790-6794. https://doi.org/10.1002/anie.201502094 1521-3773 1433-7851 https://hdl.handle.net/10481/110999 10.1002/anie.201502094 eng http://creativecommons.org/licenses/by-nc-nd/4.0/ open access Attribution-NonCommercial-NoDerivatives 4.0 Internacional Wiley