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Improved Performance of a Europium-based Metal-Organic Framework for Cyanosilylation of Demanding Ketones

dc.contributor.authorPérez, Juana M.
dc.contributor.authorEchenique Errandonea, Estitxu
dc.contributor.authorRojas Macías, Sara 
dc.contributor.authorChoquesillo Lazarte, Duane
dc.contributor.authorSeco, José M.
dc.contributor.authorLópez-Vargas, Mireya E.
dc.contributor.authorRodríguez Diéguez, Antonio 
dc.contributor.authorFernández, Ignacio
dc.date.accessioned2024-12-04T07:55:45Z
dc.date.available2024-12-04T07:55:45Z
dc.date.issued2022-10-25
dc.identifier.citationJ. M. Pérez, E. Echenique-Errandonea, S. Rojas, D. Choquesillo-Lazarte, J. M. Seco, M. E. López-Vargas, A. Rodríguez-Diéguez, I. Fernández, ChemCatChem 2022, 14, e202200967.es_ES
dc.identifier.urihttps://hdl.handle.net/10481/97676
dc.description.abstractSolvothermally promoted assembly of the multifunctional 3-amino-4-hydroxybenzoic acid ligand with the corresponding Eu salt gives rise to the formation of a porous metal-organic framework with the general formula {[Eu5L6(OH)3(H2O)3] ⋅ 5DMF}n (1) that has been tested as heterogeneous catalyst for the cyanosilylation of a broad scope of ketones in solvent-free conditions, using the lowest catalyst loading of 0.5 mol% ever reported, and exhibiting no leak and high recyclability.es_ES
dc.description.sponsorshipState Research Agency. Grant Numbers: CTQ2017-84334-R, PGC2018-102052-B−C21es_ES
dc.description.sponsorshipSpanish Ministry of Science, Innovation and Universitieses_ES
dc.description.sponsorshipEuropean Union (European Regional Development Fund – ERDF)es_ES
dc.description.sponsorshipJunta de Andalucía. Grant Numbers: 102 C2000004, CV20-78799, P20_01041, UAL-FEDER UAL2020-AGR−B1781, FQM-376, FQM-394es_ES
dc.description.sponsorshipGobierno de España. Grant Numbers: MCIN/AEI/10.13039/501100011033/Unión Europea “Next GenerationEU”/PRTR, PDC2021-121248-I00, PLEC2021-007774es_ES
dc.description.sponsorshipGovernment of the Basque Countryes_ES
dc.description.sponsorshipJuan de la Cierva Incorporación. Grant Number: IJC2019-038894-Ies_ES
dc.description.sponsorshipHipatia fellowship (University of Almería, grant no. HIPATIA2021 04).es_ES
dc.language.isoenges_ES
dc.publisherWileyes_ES
dc.rightsAtribución 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectcyanosilylationes_ES
dc.subjecteuropium es_ES
dc.subjectheterogeneous catalysises_ES
dc.titleImproved Performance of a Europium-based Metal-Organic Framework for Cyanosilylation of Demanding Ketoneses_ES
dc.typejournal articlees_ES
dc.rights.accessRightsopen accesses_ES
dc.identifier.doi10.1002/cctc.202200967
dc.type.hasVersionVoRes_ES


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