A ferromagnetically coupled diphenoxo-bridged Gd3+–Mn2+ dinuclear complex with a large magneto-caloric effect †‡§

Colacio Rodríguez, Enrique; Ruiz, José; Lorusso, Giulia; K. Brechin, Euan; Evangelisti, Marco

doi:10.1039/C3CC41483C

c3cc41483c.pdf (1.460Mb)

Identificadores

URI: https://hdl.handle.net/10481/95656

DOI: 10.1039/C3CC41483C

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Editorial

Royal Society of Chemistry

Date

2013-03-22

Referencia bibliográfica

Colacio Rodríguez, E. et. al. Chem. Commun., 2013, 49, 3845. [https://doi.org/10.1039/C3CC41483C]

Sponsorship

MINECO (contracts MAT2012-38318-C03 and CTQ2011-24478); Marie Curie-IEF (PIEF-GA-2011- 299356)

Abstract

A novel diphenoxo-bridged Gd3+–Mn2+ dimer is proposed as a good candidate for cryogenic magnetic refrigeration. The large MCE is enhanced by the ferromagnetic interaction between the two metal ions.

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