dc.contributor.author | Echenique Errandonea, Estitxu | |
dc.contributor.author | Rojas Macías, Sara | |
dc.contributor.author | Ortuño Guzmán, Ana María | |
dc.contributor.author | Cepeda, Javier | |
dc.contributor.author | Ramos-Cabrer, Pedro | |
dc.contributor.author | Vitorica-Yrezabal, Iñigo Javier | |
dc.contributor.author | Cuerva Carvajal, Juan Manuel | |
dc.contributor.author | Seco, José M. | |
dc.contributor.author | Rodríguez Diéguez, Antonio | |
dc.date.accessioned | 2024-05-14T11:31:33Z | |
dc.date.available | 2024-05-14T11:31:33Z | |
dc.date.issued | 2024-04-30 | |
dc.identifier.citation | Chem. Eur. J. 2024, e202304146 [doi.org/10.1002/chem.202304146] | es_ES |
dc.identifier.uri | https://hdl.handle.net/10481/91766 | |
dc.description | CCDC 2332735–2332740 contain the supplementary crystallographic
data for this paper, which are provided free of charge
by the Cambridge Crystallographic Data Centre | es_ES |
dc.description.abstract | In this work a family of multidimensional (2-(1H-tetrazol-5-yl)ethyl) amino acid coordination compounds have been synthesized and thoroughly characterized. For this purpose, glycine, valine, phenylalanine and tyrosine have been selected as starting amino acids and Mn2+, Zn2+ and Cd2+ as metallic nodes. From one side, for Mn2+ based dimer magnetic resonance imaging studies have been conducted, prompted by the number and disposition of the coordinated water molecules and taking into consideration the promising future of manganese-based coordination compounds as bio-compatible substitutes to conventional Gd based contrast agents. From another side, d10 block metal-based complexes allowed exploring photoluminescence properties derived by in situ synthesized ligands. Finally, amino acid preserved structural chirality allowed us to examine chiroptical properties, particularly focusing on circularly polarized luminescence. | es_ES |
dc.description.sponsorship | University of the Basque Country
(GIU20/028) | es_ES |
dc.description.sponsorship | Gobierno Vasco/Eusko Jaurlaritza (IT1755-22) | es_ES |
dc.description.sponsorship | Junta de Andalucía (FQM-394 and P21_00386) | es_ES |
dc.description.sponsorship | Ministerio de Ciencia e Innovación for a Ramón y Cajal contract
(RYC2021-032522-I funded by MCIN/AEI/10.13039/
501100011033) | es_ES |
dc.description.sponsorship | European Union «Next Generation-
EU»/PRTR») | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Wiley | es_ES |
dc.rights | Atribución 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | * |
dc.title | Multifunctional Amino Acid Derivative Coordination Compounds: Novel Contrast Agent and Luminescence Materials | es_ES |
dc.type | journal article | es_ES |
dc.rights.accessRights | open access | es_ES |
dc.identifier.doi | 10.1002/chem.202304146 | |
dc.type.hasVersion | VoR | es_ES |