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Zirconium-metal–organic framework@activated carbon composites for prevention of secondary emission of nerve agents
dc.contributor.author | Perona, Cristina | |
dc.contributor.author | Borrego Marin, Emilio | |
dc.contributor.author | Delgado López, Pedro José | |
dc.contributor.author | Vismara, Rebecca | |
dc.contributor.author | Rodríguez Maldonado, Carmen | |
dc.contributor.author | Barea Martínez, Elisa María | |
dc.contributor.author | Bandosz, Teresa J. | |
dc.contributor.author | Rodríguez Navarro, Jorge Andrés | |
dc.date.accessioned | 2024-04-19T09:30:19Z | |
dc.date.available | 2024-04-19T09:30:19Z | |
dc.date.issued | 2023-12-04 | |
dc.identifier.citation | Perona, C., Borrego-Marin, E., Delgado, P., Vismara, R., Maldonado, C. R., Barea, E., ... & Navarro, J. A. Zirconium-metal–organic framework@ activated carbon composites for prevention of secondary emission of nerve agents. J. Mater. Chem. A, 2024,12, 1772-1778 [10.1039/d3ta06108f] | es_ES |
dc.identifier.uri | https://hdl.handle.net/10481/90923 | |
dc.description.abstract | We have studied the formation of core–shell hybrid metal–organic framework@activated carbon sphere (MOF@AC) adsorbents, by means of a layer-by-layer (LBL) growth method of MOFs on shaped AC materials. The hybrid MOF@AC materials are useful for preventing the secondary emission problems of chemical warfare agent protective filters. Mesopores on AC materials facilitate carbon surface oxidation and a subsequent MOF growth, allowing Zr6O4(OH)4(benzene-1,4-dicarboxylate-2-X)6 (X = H, UiO-66; X = NH2, UiO-66-NH2) thin film formation. By contrast, microporous spheres do not allow a significant MOF layer growth. The MOF@AC hybrids are able to capture the G-type nerve agent surrogate, diisopropylfluorophosphate (DIFP), and quantitatively hydrolyse a P–F bond, within 24 h at room temperature, to yield non-toxic diisopropylphosphate (DIP) in unbuffered moist media. Neither the MOF nor the carbon spheres alone can hydrolyse the model toxic compound to that extent. The enhanced performance of the MOF@AC composites is attributed to a synergistic interplay of the hydrolytic degradation of DIFP at the MOF layer and the physisorption of DIP at the carbon pore structure, allowing the regeneration of the MOF catalytic sites. | es_ES |
dc.description.sponsorship | Spanish MCIN/AEI/10.13039/ 501100011033 (Project PID2020-113608RB-I00; TED2021- 129886B-C41) | es_ES |
dc.description.sponsorship | Spanish MCIN/AEI/10.13039/ 501100011033 by PRE2021-099867 | es_ES |
dc.description.sponsorship | Grant PRE2018-084220 funded by Spanish MCIN/AEI/10.13039/ 501100011033 and FSE | es_ES |
dc.description.sponsorship | Plan Propio de Investigación-Universidad de Granada for a predoctoral fellowship | es_ES |
dc.description.sponsorship | Plan Propio de Investigación- Universidad de Granada for a Visiting Scholar Grant | es_ES |
dc.description.sponsorship | Programa Juan de la Cierva Formación (FJC2020- 045043-I) | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Royal Society of Chemistry | es_ES |
dc.rights | Atribución-NoComercial 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc/4.0/ | * |
dc.title | Zirconium-metal–organic framework@activated carbon composites for prevention of secondary emission of nerve agents | es_ES |
dc.type | journal article | es_ES |
dc.rights.accessRights | open access | es_ES |
dc.identifier.doi | 10.1039/d3ta06108f | |
dc.type.hasVersion | VoR | es_ES |