Dry Laser-Induced Graphene Fractal-like ECG Electrodes
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Houeix, Yann; Gerardo, Denice; Romero Maldonado, Francisco Javier; Toral López, Víctor; Hernandez, Lidia; Rivadeneyra Torres, Almudena; Castillo Morales, María Encarnación; Morales Santos, Diego Pedro; Rodríguez Santiago, NoelEditorial
Wiley-VCH GmbH
Date
2024-01-15Referencia bibliográfica
Y. Houeix, D. Gerardo, F. J. Romero, V. Toral, L. Hernandez, A. Rivadeneyra, E. Castillo, D. P. Morales, N. Rodriguez, Dry Laser-Induced Graphene Fractal-like ECG Electrodes. Adv. Electron. Mater. 2024, 2300767. https://doi.org/10.1002/aelm.202300767
Sponsorship
Grant PID2020-117344RB-I00 funded by MCIN/AEI 10.13039/501100011033; FEDER/Junta de Andalucía-Consejería de Transformación Económica, Industria, Conocimiento y Universidades Project P20_00265 and Project BRNM-680-UGR20; Project TED2021-129949A-I00 funded by MCIN/AEI/10.13039/501100011033 and by European Union NextGenerationEU/ PRTR; Junta de Andalucía – Consejería de Universidad, Investigación e Innovación through the project ProyExcel_00268; Spanish Ministry of Sciences and Innovation through the Ramón y Cajal fellow RYC2019- 027457-I and the pre-doctoral grant PRE2021-096886Abstract
Fractal-like geometries applied to biosignal-electrodes design show great
potential for enhancing the signal acquisition of sensing systems. This study
reports a novel approach for flexible, silver-free, and dry fractal-like electrodes
based on Laser-Induced Graphene (LIG) obtained through laser photothermal
processing of a commercial polyimide film. This one-step mask-less
manufacturing process enables the simple fabrication of natural and
optimized fractal-like shapes inspired by actual snowflake patterns. To ensure
a reliable and standardized connection to the measurement unit, the
electrodes are equipped with a snap terminal. The electrodes are structurally
characterized using various techniques including Scanning Electron
Microscopy (SEM), Raman spectroscopy, and X-ray Photoelectron
Spectroscopy (XPS). By benchmarking the performance of these electrodes
against Ag/AgCl wet commercial electrodes and LIG electrodes shaped as
commercial ones, a heart rate-monitoring accuracy of over 96.8% is achieved,
with high specificity, positive prediction, and sensitivity, surpassing the 95.8%
achieved by conventional commercial electrodes. These results demonstrate
the efficacy of fractal-based designs in combination with LIG-based
transduction, offering flexible and cost-effective electrocardiogram (ECG)
electrodes with improved performance compared to traditional wet electrodes.