Effect of noble metal addition over active Ru/TiO2 catalyst for CO selective methanation from H2 rich-streams
Metadatos
Mostrar el registro completo del ítemEditorial
Elsevier
Materia
H2 purification CO selective methanation Ru-based catalyst Noble metals addition
Fecha
2023-07-29Referencia bibliográfica
Bobadilla, L. F. et al. Effect of noble metal addition over active Ru/TiO2 catalyst for CO selective methanation from H2 rich-streams. International Journal of Hydrogen Energy vol. 48, nº 64, 25065-25074. [https://doi.org/10.1016/j.ijhydene.2022.07.072]
Patrocinador
Spanish Government RTI2018-096294-B-C33; European Union (EU); Junta de Andalucia US-1263288Resumen
Selective CO methanation from H2-rich stream has been regarded as a promising route for deep removal of low CO concentration and catalytic hydrogen purification processes. This work is focused on the development of more efficient catalysts applied in practical conditions. For this purpose, we prepared a series of catalysts based on Ru supported over titania and promoted with small amounts of Rh and Pt. Characterization details revealed that Rh and Pt modify the electronic properties of Ru. The results of catalytic activity showed that Pt has a negative effect since it promotes the reverse water gas shift reaction decreasing the selectivity of methanation but Rh increases remarkably the activity and selectivity of CO methanation. The obtained results suggest that RuRh-based catalyst could become important for the treatment of industrial-volume streams.