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A mesoporous Zr-based metal–organic framework driven by the assembly of an octatopic linker
dc.contributor.author | Ortín Rubio, Borja | |
dc.contributor.author | Carmona Fernández, Francisco Jesús | |
dc.date.accessioned | 2023-06-28T09:26:52Z | |
dc.date.available | 2023-06-28T09:26:52Z | |
dc.date.issued | 2023-06-20 | |
dc.identifier.citation | Chem. Commun., 2023, 59, 7803[DOI: 10.1039/d3cc01831h] | es_ES |
dc.identifier.uri | https://hdl.handle.net/10481/82918 | |
dc.description.abstract | Metal–organic frameworks (MOFs) based on high-connected nets are generally very attractive due to their combined robustness and porosity. Here, we describe the synthesis of BCN-348, a new high-connected Zr-MOF built from an 8-connected (8-c) cubic Zroxocluster and an 8-c organic linker. BCN-348 contains a minimal edge-transitive 3,4,8-c eps net, and combines mesoporosity with thermal and hydrolytic stability. Encouraging results from preliminary studies on its use as a catalyst for hydrolysis of a nerve-agent simulant suggest its potential as an agent for detoxification of chemical weapons and other pernicious compounds. | es_ES |
dc.description.sponsorship | European Union’s Horizon 2020 research and innovation programme, under grant agreement No 101019003 | es_ES |
dc.description.sponsorship | Catalan AGAUR (project 2021 SGR 00458) | es_ES |
dc.description.sponsorship | the CERCA Programme/Generalitat de Catalunya, and the Spanish MCIN/AEI/10.13039/501100011033 (Project PID2020-113608RB-I00 | es_ES |
dc.description.sponsorship | ICN2 is supported by the Severo Ochoa Centres of Excellence programme | es_ES |
dc.description.sponsorship | Grant CEX2021- 001214-S, funded by MCIN/AEI/10.13039.501100011033 | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Royal Society of Chemstry | es_ES |
dc.rights | Atribución 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | * |
dc.title | A mesoporous Zr-based metal–organic framework driven by the assembly of an octatopic linker | es_ES |
dc.type | journal article | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/101019003 | es_ES |
dc.rights.accessRights | open access | es_ES |
dc.identifier.doi | 10.1039/d3cc01831h | |
dc.type.hasVersion | VoR | es_ES |
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