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Rational design of carborane-based Cu2-paddle wheel coordination polymers for increased hydrolytic stability

dc.contributor.authorLi, Zhen
dc.contributor.authorChoquesillo Lazarte, Duane
dc.contributor.authorFraile, Julio
dc.contributor.authorViñas, Clara
dc.contributor.authorTeixidor, Francesc
dc.contributor.authorPlanas, José G.
dc.date.accessioned2022-02-11T12:27:46Z
dc.date.available2022-02-11T12:27:46Z
dc.date.issued2021-12-09
dc.identifier.citationDalton Trans., 2022, 51, 1137. [DOI 10.1039/d1dt04065k]es_ES
dc.identifier.urihttp://hdl.handle.net/10481/72801
dc.descriptionThis work was financially supported by MICINN (PID2019-106832RB-I00), MICINN through the Severo Ochoa Program for Centers of Excellence for the FUNFUTURE (CEX2019-000917-S project) and the Generalitat de Catalunya (2017/SGR/1720). D. Ch.-L. acknowledges funding by project no. PGC2018-102047-B-I00 (MCIU/AEI/FEDER, UE). Zhen Li is enrolled in the UAB PhD program and acknowledges the China Scholarship Council (CSC) for his PhD grant (201808310071).es_ES
dc.description.abstractA new unsymmetric carborane-based dicarboxylic linker provided a 1D Cu2-paddle wheel coordination polymer (2) with much higher hydrolytic stability than the corresponding 2D Cu2-paddle wheel polymer (1), obtained from a related more symmetrical carborane-based linker. Both 1 and 2 were used as efficient heterogeneous catalysts for a model aza-Michael reaction but only 2 can be reused several times without significant degradation in catalytic activity.es_ES
dc.language.isoenges_ES
dc.publisherRoyal Society of Chemistryes_ES
dc.rightsAtribución-NoComercial 3.0 España*
dc.rights.urihttp://creativecommons.org/licenses/by-nc/3.0/es/*
dc.titleRational design of carborane-based Cu2-paddle wheel coordination polymers for increased hydrolytic stabilityes_ES
dc.typejournal articlees_ES
dc.rights.accessRightsopen accesses_ES
dc.identifier.doi10.1039/d1dt04065k
dc.type.hasVersionVoRes_ES


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