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dc.contributor.authorMeazza, Marta
dc.contributor.authorMoreno Cruz, Carlos
dc.contributor.authorOrtuño Guzmán, Ana María 
dc.contributor.authorCuerva Carvajal, Juan Manuel 
dc.contributor.authorCrovetto González, Luis 
dc.date.accessioned2021-05-05T07:38:01Z
dc.date.available2021-05-05T07:38:01Z
dc.date.issued2021
dc.identifier.citationChem. Sci., 2021, 12, 4503. [DOI: 10.1039/d0sc06574a]es_ES
dc.identifier.urihttp://hdl.handle.net/10481/68318
dc.description.abstractThe first enantioselective addition of alkyl BODIPYs to Morita–Baylis–Hillman (MBH) carbonates is reported. This is the first reported enantioselective methodology using the methylene position of BODIPYs as a nucleophile. The reaction is efficiently catalyzed by cinchona alkaloids, achieving high enantioselectivities and total diastereoselectivity. The use of cinchona alkaloid pseudo enantiomers (chinine/cinchonine) allows us to obtain both pairs of enantiomers in similar yields and enantioselectivities, a common issue in this type of reaction. The photophysical study of these dyes (absorption and fluorescence) has been performed in order to determine their parameters and explore future possible application in bioimaging. In addition, electronic circular dichroism (ECD) studies supported by time-dependent density functional theory (TD-DFT) calculations were also performed.es_ES
dc.language.isoenges_ES
dc.publisherROYAL SOC CHEMISTRYes_ES
dc.rightsAtribución-NoComercial 3.0 España*
dc.rights.urihttp://creativecommons.org/licenses/by-nc/3.0/es/*
dc.titleStudying the reactivity of alkyl substituted BODIPYs: first enantioselective addition of BODIPY to MBH carbonateses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.identifier.doi10.1039/d0sc06574a


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Atribución-NoComercial 3.0 España
Except where otherwise noted, this item's license is described as Atribución-NoComercial 3.0 España