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dc.contributor.authorKotopoulou, Electra
dc.contributor.authorLópez Haro, Miguel
dc.contributor.authorCalvino Gámez, José Juan
dc.contributor.authorGarcía Ruiz, Juan Manuel 
dc.date.accessioned2021-02-09T08:57:01Z
dc.date.available2021-02-09T08:57:01Z
dc.date.issued2020-11
dc.identifier.citationKotopoulou, E., Lopez‐Haro, M., Calvino Gamez, J. J., & García‐Ruiz, J. M. (2021). Nanoscale anatomy of iron‐silica self‐organized membranes: implications for prebiotic chemistry. Angewandte Chemie, 133(3), 1416-1422. [doi.org/10.1002/anie.202012059]es_ES
dc.identifier.urihttp://hdl.handle.net/10481/66397
dc.description.abstractIron-silica self-organized membranes, so-called chemical gardens, behave as fuel cells and catalyze the formation of amino/carboxylic acids and RNA nucleobases from organics that were available on early Earth. Despite their relevance for prebiotic chemistry, little is known about their structure and mineralogy at the nanoscale. Studied here are focused ion beam milled sections of iron-silica membranes, grown from synthetic and natural, alkaline, serpentinizationderived fluids thought to be widespread on early Earth. Electron microscopy shows they comprise amorphous silica and iron nanoparticles of large surface areas and inter/intraparticle porosities. Their construction resembles that of a heterogeneous catalyst, but they can also exhibit a bilayer structure. Surface-area measurements suggest that membranes grown from natural waters have even higher catalytic potential. Considering their geochemically plausible precipitation in the early hydrothermal systems where abiotic organics were produced, iron-silica membranes might have assisted the generation and organization of the first biologically relevant organics.es_ES
dc.description.sponsorshipCentro de Instrumentacion Cientifica (CIC) of the University of Granada, Spaines_ES
dc.description.sponsorshipUniversity of Granada, Spaines_ES
dc.description.sponsorshipMINECO/FEDER MAT2017-87579-R MAT2016-81118-Pes_ES
dc.description.sponsorshipJunta de Andalucía FQM334es_ES
dc.description.sponsorshipEuropean Research Council under the Programme (FP7/2007-2013)/ERC 340863es_ES
dc.language.isoenges_ES
dc.publisherWileyes_ES
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.titleNanoscale Anatomy of Iron-Silica Self-Organized Membranes: Implications for Prebiotic Chemistryes_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/340863es_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.identifier.doi10.1002/anie.202012059
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersiones_ES


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