Smart lanthanide antennas for sensing water
Metadata
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Fueyo González, Francisco; García Fernández, Emilio; Martínez, David; Orte Gutiérrez, Ángel; González Vera, Juan AntonioEditorial
Royal Society Chemistry
Date
2020-05-21Referencia bibliográfica
Fueyo-González, F., Garcia-Fernandez, E., Martínez, D., Infantes, L., Orte, A., González-Vera, J. A., & Herranz, R. (2020). Smart lanthanide antennas for sensing water. Chemical Communications, 56(41), 5484-5487. [DOI: 10.1039/d0cc01725f]
Sponsorship
Spanish Ministerio de Economia y Competividad SAF2012-32209 FU2015-67284-R; Ministerio de Ciencia e Innovacion/Agencia Estatal de Investigacion/European Regional Development Fund CTQ2017-85658-R CTQ2015-63997-C2; Consejo Superior de Investigaciones Cientificas (CSIC) 201580E073Abstract
Two new families of lanthanide antennas are described. 8-Methoxy-
4,5-dihydrocyclopenta[de]quinolin-2(1H)-one phosphonates or
carboxylates behave as selective antennas exhibiting Eu3+ luminescence
in organic solvents, while quinolin-2(1H)-one analogues
selectively sensitize the Tb3+ emission. These emissions are quenched
by H2O addition. Based on this behaviour, the new lanthanide
antennas can be used as highly sensitive water sensors.