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dc.contributor.authorGarcía Valdivia, Antonio A.
dc.contributor.authorRamírez Rodríguez, Gloria Belén 
dc.contributor.authorDelgado-López, José M.
dc.contributor.authorRodríguez Diéguez, Antonio 
dc.date.accessioned2020-09-29T06:31:14Z
dc.date.available2020-09-29T06:31:14Z
dc.date.issued2020
dc.identifier.citationGarcía-Valdivia, A. A., Zabala-Lekuona, A., Ramírez-Rodríguez, G. B., Delgado-López, J. M., Fernández, B., Cepeda, J., & Rodríguez-Diéguez, A. (2020). 2D-Coordination polymers based on 1 H-indazole-4-carboxylic acid and transition metal ions: magnetic, luminescence and biological properties. CrystEngComm, 22(30), 5086-5095. [DOI: 10.1039/d0ce00544d]es_ES
dc.identifier.urihttp://hdl.handle.net/10481/63610
dc.description.abstractWe report the formation of five novel multifunctional coordination polymers based on 1H-indazole-4- carboxylic acid (HL). To the best of our knowledge, these complexes are the first examples of coordination compounds constructed with this interesting ligand. These materials were synthesized by solvothermal routes, possess different 2D-structures and show interesting magnetic properties due to the copper compound showing an unusual spin-canted effect while the anisotropic cobalt material behaves as a fieldinduced single molecule magnet. MTT assays performed on human embryonic kidney (HEK293) and mouse skin melanoma (B16-F10) cell lines indicated that the Cd-based compound was the only one exhibiting dose-dependent toxicity on B16-F10 cells, most likely due to the release of toxic Cd(II). Cadmium and zinc polymers exhibit interesting luminescence properties. The fact that zinc polymers did not exhibit inherent toxicity against both cancer and non-cancerous cells make this new family an excellent candidate for further investigation in the field of luminescent materials with biomedical applications.es_ES
dc.description.sponsorshipJunta de Andalucia FQM-394 FQM-1484es_ES
dc.description.sponsorshipRed Guipuzcoana de Ciencia, Tecnologia e Innovacion OF218/2018es_ES
dc.description.sponsorshipUniversity of Basque Country GIU 17/13es_ES
dc.description.sponsorshipBasque Government IT1005-16es_ES
dc.description.sponsorshipSpanish Ministry of Science, Innovation and Universities (MCIU/AEI/FEDER, UE) PGC2018-102052-A-C22 PGC2018-102052-B-C21es_ES
dc.description.sponsorshipJunta de Andalucia FQM-394 FQM-1484es_ES
dc.description.sponsorshipEuropean Union (EU)es_ES
dc.description.sponsorshipESFes_ES
dc.description.sponsorshipGovernment of the Basque Countryes_ES
dc.description.sponsorshipFEDER/MCIU/AEI RYC-2016-21042 JdC-2017es_ES
dc.language.isoenges_ES
dc.publisherRoyal Society of Chemistryes_ES
dc.rightsAtribución-NoComercial 3.0 España*
dc.rights.urihttp://creativecommons.org/licenses/by-nc/3.0/es/*
dc.title2D-Coordination polymers based on 1H-indazole4-carboxylic acid and transition metal ions: magnetic, luminescence and biological propertieses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.identifier.doi10.1039/d0ce00544d


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