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Luminescence and Magnetic Properties of Two Three-Dimensional Terbium and Dysprosium MOFs Based on Azobenzene-4,4′-Dicarboxylic Linker

dc.contributor.authorFernández, Belénes_ES
dc.contributor.authorOyarzabal, Itziares_ES
dc.contributor.authorSeco, José M.es_ES
dc.contributor.authorSan Sebastián, Eideres_ES
dc.contributor.authorFairén-Jiménez, Davides_ES
dc.contributor.authorGómez-Ruiz, Santiagoes_ES
dc.contributor.authorSalinas Castillo, Alfonso es_ES
dc.contributor.authorCalahorro Casnova, Antonio Jesúses_ES
dc.contributor.authorRodríguez Diéguez, Antonio es_ES
dc.date.accessioned2018-01-26T11:24:52Z
dc.date.available2018-01-26T11:24:52Z
dc.date.issued2016-02-02
dc.identifier.citationFernández, B.; et al. Luminescence and Magnetic Properties of Two Three-Dimensional Terbium and Dysprosium MOFs Based on Azobenzene-4,4′-Dicarboxylic Linker. Polymers, 8(2): 39 (2016). [http://hdl.handle.net/10481/49195]es_ES
dc.identifier.issn2073-4360
dc.identifier.urihttp://hdl.handle.net/10481/49195
dc.description.abstractWe report the in situ formation of two novel metal-organic frameworks based on terbium and dysprosium ions using azobenzene-4,4′-dicarboxylic acid (H2abd) as ligand, synthesized by soft hydrothermal routes. Both materials show isostructural three-dimensional networks with channels along a axis and display intense photoluminescence properties in the solid state at room temperature. Textural properties of the metal-organic frameworks (MOFs) have been fully characterized although no appreciable porosity was obtained. Magnetic properties of these materials were studied, highlighting the dysprosium material displays slightly frequency-dependent out of phase signals when measured under zero external field and under an applied field of 1000 Oe.en_EN
dc.description.sponsorshipThis work was supported by the MEC of Spain (Project CTQ2011-24478) and the Junta de Andalucía (FQM-1484 and FQM-195). David Fairen-Jiménez thanks the Royal Society for a University Research Fellowship. Itziar Oyarzabal is grateful to the Departamento de Educación, Universidades e Investigación del Gobierno Vasco for a predoctoral fellowship. The authors thank for technical and human support provided by SG Iker Gipuzkoa of UPV/EHU.en_EN
dc.language.isoenges_ES
dc.publisherMDPIes_ES
dc.subjectMetal-organic frameworken_EN
dc.subjectDysprosiumen_EN
dc.subjectTerbiumen_EN
dc.subjectMagnetism en_EN
dc.subjectLuminescence en_EN
dc.titleLuminescence and Magnetic Properties of Two Three-Dimensional Terbium and Dysprosium MOFs Based on Azobenzene-4,4′-Dicarboxylic Linkeren_EN
dc.typejournal articleen_EN
dc.rights.accessRightsopen accessen_EN
dc.identifier.doi10.3390/polym8020039


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