Recent applications of Cp2TiCl in natural product synthesis

Morcillo Martínez, Sara Patricia; Miguel Álvarez, Delia; González Campaña, Araceli; Álvarez Cienfuegos Rodríguez, Luis; Justicia Ladrón De Guevara, José; Cuerva Carvajal, Juan Manuel

doi:10.1039/C3QO00024A

MorcilloMartinez_TitanoceneIII.pdf (1.100Mb)

Identificadores

URI: http://hdl.handle.net/10481/47295

DOI: 10.1039/C3QO00024A

ISSN: 2052-4110

ISSN: 2052-4129

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Editorial

Royal Society of Chemistry

Materia

Titanocene

Catalytic methods

Natural products

Synthesis

Terpenes

Date

2014-01-27

Referencia bibliográfica

Morcillo Martínez, S.P.; et al. Recent applications of Cp2TiCl in natural product synthesis. Organic Chemistry Frontiers, 1: 15-33 (2014). [doi: 10.1039/C3QO00024A]

Sponsorship

We thank the Regional Government of Andalucía (project P09-FQM-4571), MICINN (project CTQ-2011.22455), and CEI-Biotic for financial support. SPM thanks the Regional Government of Andalucía for her FPI fellowship. DM and AGC thank the Regional Government of Andalucía and the MICINN ( Juan de la Cierva) for their postdoctoral contracts.

Abstract

This review highlights the recent applications of titanocene(III) complexes in the field of natural product synthesis from the seminal precedents to the development of modern catalytic methods. The power of the titanocene(III)-based approaches is demonstrated by the straightforward syntheses of many natural products from readily available starting materials.

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