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dc.contributor.authorCastillo Santaella, Teresa del es_ES
dc.contributor.authorMaldonado Valderrama, Julia es_ES
dc.contributor.authorFaraudo Gener, Jordies_ES
dc.contributor.authorMartín-Molina, Albertoes_ES
dc.date.accessioned2017-02-22T12:01:27Z
dc.date.available2017-02-22T12:01:27Z
dc.date.issued2016
dc.identifier.citationCastillo-Santaella, T. [et al]. A. Specific Ion Effects in Cholesterol Monolayers. Materials 2016, 9, 340. [http://hdl.handle.net/10481/45003]es_ES
dc.identifier.issn1996-1944
dc.identifier.urihttp://hdl.handle.net/10481/45003
dc.description.abstractThe interaction of ions with interfaces and, in particular, the high specificity of these interactions to the particular ions considered, are central questions in the field of surface forces. Here we study the effect of different salts (NaI, NaCl, CaCl2 and MgCl2) on monolayers made of cholesterol molecules, both experimentally (surface area vs. lateral pressure isotherms measured by a Langmuir Film Balance) and theoretically (molecular dynamics (MD) all-atomic simulations). We found that surface isotherms depend, both quantitatively and qualitatively, on the nature of the ions by altering the shape and features of the isotherm. In line with the experiments, MD simulations show clear evidences of specific ionic effects and also provide molecular level details on ion specific interactions with cholesterol. More importantly, MD simulations show that the interaction of a particular ion with the surface depends strongly on its counterion, a feature ignored so far in most theories of specific ionic effects in surface forces.es_ES
dc.language.isospaes_ES
dc.publisherMDPIes_ES
dc.rightsCreative Commons Attribution-NonCommercial-NoDerivs 3.0 Licensees_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es_ES
dc.subjectIonic specificityes_ES
dc.subjectCholesterol es_ES
dc.subjectLangmuir monolayerses_ES
dc.subjectMolecular dynamics simulationses_ES
dc.subjectSurface forceses_ES
dc.titleSpecific Ion Effects in Cholesterol Monolayerses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES


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