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A Configurationally Stable Helical Indenofluorene

dc.contributor.authorMartínez Pinel, Álvaro 
dc.contributor.authorLezama, Luis
dc.contributor.authorCuerva Carvajal, Juan Manuel 
dc.contributor.authorCasares López, Raquel 
dc.contributor.authorBlanco Suárez, Víctor 
dc.contributor.authorMoreno Cruz, Carlos 
dc.contributor.authorMillán Delgado, Alba 
dc.date.accessioned2025-07-11T11:41:16Z
dc.date.available2025-07-11T11:41:16Z
dc.date.issued2024-07-05
dc.identifier.citationMartínez-Pinel, Á., Lezama, L., Cuerva, J. M., Casares, R., Blanco, V., Cruz, C. M., & Millán, A. (2024). A configurationally stable helical indenofluorene. Organic Letters, 26(28), 6012–6017. https://doi.org/10.1021/acs.orglett.4c02128es_ES
dc.identifier.urihttps://hdl.handle.net/10481/105218
dc.description.abstractWe report the synthesis and study of the optoelectronic, magnetic, and chiroptical properties of a helically chiral diradicaloid based on dibenzoindeno[2,1-c]fluorene. The molecule shows a small HOMO–LUMO gap and a moderate singlet–triplet gap, which agrees with the results of DFT calculations. The helical structure of the compound, confirmed by X-ray diffraction, is configurationally stable, which allows the isolation of both enantiomers and the evaluation of the chiroptical properties (ECD).es_ES
dc.description.sponsorshipERDF y MICIU/AEI/10.13039/501100011033 (PID2021-127964NB-C22, PID2022-137403NA-I00)es_ES
dc.description.sponsorshipMinisterio de Universidades (FPU19/03751)es_ES
dc.description.sponsorshipMICIU/AEI/10.13039/501100011033 and “ESF Investing in your future” (PRE2018- 083406)es_ES
dc.description.sponsorshipUniversidad de Granada/ CBUAes_ES
dc.language.isoenges_ES
dc.publisherAmerican Chemical Societyes_ES
dc.rightsAtribución 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.titleA Configurationally Stable Helical Indenofluorenees_ES
dc.typejournal articlees_ES
dc.rights.accessRightsopen accesses_ES
dc.identifier.doi10.1021/acs.orglett.4c02128
dc.type.hasVersionVoRes_ES


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