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Surface Functionalization of Metal−Organic Framework Crystals with Catechol Coatings for Enhanced Moisture Tolerance

dc.contributor.authorCastells-Gil, Javier
dc.contributor.authorNovio, Fernando
dc.contributor.authorMuñoz Padial, Natalia 
dc.contributor.authorTatay, Sergio
dc.contributor.authorRuíz-Molina, Daniel
dc.contributor.authorMartí-Gastaldo, Carlos
dc.date.accessioned2025-01-30T09:36:04Z
dc.date.available2025-01-30T09:36:04Z
dc.date.issued2017-11-28
dc.identifier.citationACS Appl. Mater. Interfaces, 2017, 9 (51), 44641–44648es_ES
dc.identifier.urihttps://hdl.handle.net/10481/101155
dc.description.abstractRobust catechol coatings for enhanced moisture tolerance were produced in one step by direct reaction of Hong Kong University of Science and Technology (HKUST) with synthetic catechols. We ascribe the rapid formation of homogeneous coatings around the metal−organic framework particles to the biomimetic catalytic activity of Cu(II) dimers in the external surface of the crystals. Use of fluorinated catechols results in hydrophobic, permeable coatings that protect HKUST from water degradation while retaining close to 100% of its original sorption capacity.es_ES
dc.description.sponsorshipThis work was ACKNOWLEDGMENTS supported by the EU (ERC Stg Chem-fs-MOF 714122), Spanish MINECO (Unit of Excellence Marıa de Maeztu MDM-2015-0538), and the Generalitat Valenciana (Grant GV/2016/137). C.M.-G. and J.C.-G. thank the Spanish MINECO for a Ramon y Cajal Fellowship and FPI Scholarship (CTQ2014-59209-P), respectively. N.M.P. thanks the Junta de Andalucıa for postdoctoral fellowship P10-FQM-6050. F.N. and D.R.M. are also grateful to the financial support offered by Project MAT2015-70615-R from the Spanish Government and by FEDER funds. The ICN2 is funded by the CERCA programme/Generalitat de Catalunya and supported by the Severo Ochoa programme of the Spanish Ministry of Economy, Industry and Competitiveness (MINECO, grant no. SEV-20130295).es_ES
dc.language.isoenges_ES
dc.publisherAmerican Chemical Societyes_ES
dc.rightsCreative Commons Attribution-NonCommercial-NoDerivs 3.0 License
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/
dc.titleSurface Functionalization of Metal−Organic Framework Crystals with Catechol Coatings for Enhanced Moisture Tolerancees_ES
dc.typejournal articlees_ES
dc.rights.accessRightsopen accesses_ES
dc.identifier.doi10.1021/acsami.7b15564
dc.type.hasVersionAMes_ES


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