@misc{10481/97676, year = {2022}, month = {10}, url = {https://hdl.handle.net/10481/97676}, abstract = {Solvothermally promoted assembly of the multifunctional 3-amino-4-hydroxybenzoic acid ligand with the corresponding Eu salt gives rise to the formation of a porous metal-organic framework with the general formula {[Eu5L6(OH)3(H2O)3] ⋅ 5DMF}n (1) that has been tested as heterogeneous catalyst for the cyanosilylation of a broad scope of ketones in solvent-free conditions, using the lowest catalyst loading of 0.5 mol% ever reported, and exhibiting no leak and high recyclability.}, organization = {State Research Agency. Grant Numbers: CTQ2017-84334-R, PGC2018-102052-B−C21}, organization = {Spanish Ministry of Science, Innovation and Universities}, organization = {European Union (European Regional Development Fund – ERDF)}, organization = {Junta de Andalucía. Grant Numbers: 102 C2000004, CV20-78799, P20_01041, UAL-FEDER UAL2020-AGR−B1781, FQM-376, FQM-394}, organization = {Gobierno de España. Grant Numbers: MCIN/AEI/10.13039/501100011033/Unión Europea “Next GenerationEU”/PRTR, PDC2021-121248-I00, PLEC2021-007774}, organization = {Government of the Basque Country}, organization = {Juan de la Cierva Incorporación. Grant Number: IJC2019-038894-I}, organization = {Hipatia fellowship (University of Almería, grant no. HIPATIA2021 04).}, publisher = {Wiley}, keywords = {cyanosilylation}, keywords = {europium}, keywords = {heterogeneous catalysis}, title = {Improved Performance of a Europium-based Metal-Organic Framework for Cyanosilylation of Demanding Ketones}, doi = {10.1002/cctc.202200967}, author = {Pérez, Juana M. and Echenique Errandonea, Estitxu and Rojas Macías, Sara and Choquesillo Lazarte, Duane and Seco, José M. and López-Vargas, Mireya E. and Rodríguez Diéguez, Antonio and Fernández, Ignacio}, }