@misc{10481/97131,
year = {2022},
month = {7},
url = {https://hdl.handle.net/10481/97131},
abstract = {Electrically conductive metal–organic frameworks (MOFs) have emerged in the past few years as promising
materials towards applications in (opto)electronics, electrocatalysis and energy storage, among others. One of
the most common strategies for the design of conductive MOFs is based on the use of electroactive organic
ligands and their partial oxidation/reduction to increase the number of charge carriers. Although perylene salts
were reported as the first molecular conductors, they have been scarcely explored as building blocks for the
construction of conductive MOFs. Herein we report the electrical conductivity enhancement of a
microporous perylene-based MOF upon partial ligand oxidation by using two-probe single-crystal devices.
The origin of the conductivity enhancement is rationalised by means of spectroscopic studies and quantumchemical
calculations, supporting a through-space hopping transport along the herringbone perylene
packing. This study opens the way for the design of conductive MOFs based on perylene building blocks.},
organization = {Project
CICECO-Aveiro Institute of Materials, Grants UIDB/50011/
2020 and UIDP/50011/2020, financed by national funds
through the FCT/MEC and when appropriate co-financed by
FEDER under the PT2020 Partnership Agreement},
organization = {FCT for funding the project PTDC/QUI-ELT/2593/2021},
organization = {Spanish government (PID2020-119748GA-I00,
funded by MICIN/AEI/10.13039/501100011033, and the Maria
de Maeztu CEX2019-000919-M grant)},
organization = {Generalitat
Valenciana (GV/2021/027, GVPROMETEO2020-077)},
organization = {PhD grant (2020.08520.BD)},
organization = {PhD grant (2020.06159.BD)},
organization = {Junior Researcher Position
(CEECIND/00546/2018)},
publisher = {Royal Society of Chemistry},
title = {Through-space hopping transport in an iodinedoped perylene-based metal–organic framework},
doi = {10.1039/D2ME00108J},
author = {Valente, Gonçalo and Rochina, María Esteve and Paracana, Ana and Rodríguez Diéguez, Antonio and Choquesillo Lazarte, Duane and Ortí, Enrique and Calbo, Joaquín and Ilkaeva, Marina and Mafra, Luís and Hernández-Rodríguez, Miguel A. and Rocha, João and Alves, Helena and Souto, Manuel},
}