@misc{10481/93569,
year = {2024},
month = {6},
url = {https://hdl.handle.net/10481/93569},
abstract = {Two novel Ce(III) metal organic frameworks (MOFs) with formulas [Ce(5Meip)(H-5Meip)]nGR-MOF-17 and [CeCl(5Meip)(DMF)]nGR-MOF-18 (5Meip = 5-methylisophthalate, DMF = N,N-dimethylformamide) have been synthesized, forming 3-dimensional frameworks. Magnetic measurements show that both compounds present field-induced slow magnetic relaxation under a small applied dc field. For GR-MOF-17, the temperature dependence of relaxation times is best described by a Raman mechanism, whereas for GR-MOF-18, relaxation occurs through a combination of Raman and local-mode pathways. Moreover, when avoiding short Ce⋯Ce interactions by magnetic dilution in GR-MOF-17@La and GR-MOF-18@La, only the local-mode mechanism is responsible for magnetic relaxation. Photophysical studies show the occurrence of ligand-centred luminescence in both compounds and phosphorescence emission at low temperature for GR-MOF-17.},
organization = {Gobierno Vasco/Eusko
Jaurlaritza (IT1755-22, IT1500-22), Red Guipuzcoana de
Ciencia, Tecnología e Innovación (FA385/2023, DG23/16)},
organization = {Junta de Andalucía (FQM-394, P21_00386 and
ProyExcel_00386)},
organization = {SGIker of UPV/EHU and European
funding (ERDF and ESF)},
organization = {Ministerio de Ciencia e
Innovación for a Ramón y Cajal contract (the publication is
part of the grant RYC2021-032522-I funded by MCIN/AEI/
10.13039/501100011033 and the European Union “Next
Generation-EU”/PRTR”)},
publisher = {Royal Society of Chemistry},
title = {Cerium(III) and 5-methylisophthalate-based MOFs with slow relaxation of magnetization and photoluminescence emission},
doi = {10.1039/d4dt00401a},
author = {Pajuelo Corral, Oier and Contreras, M. Carmen and Rojas Macías, Sara and Choquesillo Lazarte, Duane and José M. Seco, José M. and Rodríguez Diéguez, Antonio and Salinas-Castillo, Alfonso and Cepeda, Javier and Zabala-Lekuona, Andoni Zabala-Lekuona and Vitorica-Yrezabal, Iñigo J.},
}