@misc{10481/91766,
year = {2024},
month = {4},
url = {https://hdl.handle.net/10481/91766},
abstract = {In this work a family of multidimensional (2-(1H-tetrazol-5-yl)ethyl) amino acid coordination compounds have been synthesized and thoroughly characterized. For this purpose, glycine, valine, phenylalanine and tyrosine have been selected as starting amino acids and Mn2+, Zn2+ and Cd2+ as metallic nodes. From one side, for Mn2+ based dimer magnetic resonance imaging studies have been conducted, prompted by the number and disposition of the coordinated water molecules and taking into consideration the promising future of manganese-based coordination compounds as bio-compatible substitutes to conventional Gd based contrast agents. From another side, d10 block metal-based complexes allowed exploring photoluminescence properties derived by in situ synthesized ligands. Finally, amino acid preserved structural chirality allowed us to examine chiroptical properties, particularly focusing on circularly polarized luminescence.},
organization = {University of the Basque Country
(GIU20/028)},
organization = {Gobierno Vasco/Eusko Jaurlaritza (IT1755-22)},
organization = {Junta de Andalucía (FQM-394 and P21_00386)},
organization = {Ministerio de Ciencia e Innovación for a Ramón y Cajal contract
(RYC2021-032522-I funded by MCIN/AEI/10.13039/
501100011033)},
organization = {European Union «Next Generation-
EU»/PRTR»)},
publisher = {Wiley},
title = {Multifunctional Amino Acid Derivative Coordination Compounds: Novel Contrast Agent and Luminescence Materials},
doi = {10.1002/chem.202304146},
author = {Echenique Errandonea, Estitxu and Rojas Macías, Sara and Ortuño Guzmán, Ana María and Cepeda, Javier and Ramos-Cabrer, Pedro and Vitorica-Yrezabal, Iñigo Javier and Cuerva Carvajal, Juan Manuel and Seco, José M. and Rodríguez Diéguez, Antonio},
}