@misc{10481/91249,
year = {2023},
month = {12},
url = {https://hdl.handle.net/10481/91249},
abstract = {The impact of solution stoichiometry on the
nucleation and growth of BaSO4 was studied by measuring
solution transmittance and subsequent fitting to a crystallization
model. Our results show that a large excess of either Ba2+ or SO4 2−
ions inhibits both the nucleation and growth of BaSO4. However,
for a small excess of Ba2+, the growth is enhanced. The dependence
of nucleation and growth rates on supersaturation and solution
stoichiometry was captured by a semiempirical rate model. Hence,
the solution stoichiometry is a highly relevant parameter while
studying all aspects of BaSO4 crystallization, and it could be
worthwhile to examine other minerals similarly.},
organization = {European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (grant agreement no. 819588)},
organization = {Junta de Andalucía (PROYEXCEL_00771)},
publisher = {American Chemical Society},
title = {Effect of Solution Stoichiometry on BaSO4 Crystallization from Turbidity Measurements and Modeling},
doi = {10.1021/acs.iecr.3c03612},
author = {Peters, Vincent F. D. and Baken, A. and Seepma, S. Y. M. H. and Koskamp, J. A. and Fernández Martínez, Alejandro and Van Driessche, Alexander Edgard Suzanne and Wolthers, M.},
}